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2011


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Quantum-Cascade Laser-Based Vibrational Circular Dichroism

Luedeke, S., Pfeifer, M., Fischer, P.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133(15):5704-5707, 2011 (article)

Abstract
Vibrational circular dichroism (VCD) spectra were recorded with a tunable external-cavity quantum-cascade laser (QCL). In comparison with standard thermal light sources in the IR, QCLs provide orders of magnitude more power and are therefore promising for VCD studies in strongly absorbing solvents. The brightness of this novel light source is demonstrated with VCD and IR absorption measurements of a number of compounds, including proline in water.

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DOI [BibTex]

2011


DOI [BibTex]


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Actively coupled cavity ringdown spectroscopy with low-power broadband sources

Petermann, C., Fischer, P.

OPTICS EXPRESS, 19(11):10164-10173, 2011 (article)

Abstract
We demonstrate a coupling scheme for cavity enhanced absorption spectroscopy that makes use of an intracavity acousto-optical modulator to actively switch light into (and out of) a resonator. This allows cavity ringdown spectroscopy (CRDS) to be implemented with broadband nonlaser light sources with spectral power densities of less than 30 mu W/nm. Although the acousto-optical element reduces the ultimate detection limit by introducing additional losses, it permits absorptivities to be measured with a high dynamic range, especially in lossy environments. Absorption measurements for the forbidden transition of gaseous oxygen in air at similar to 760nm are presented using a low-coherence cw-superluminescent diode. The same setup was electronically configured to cover absorption losses from 1.8 x 10(-8)cm(-1) to 7.5\% per roundtrip. This could be of interest in process analytical applications. (C) 2011 Optical Society of America

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DOI [BibTex]

DOI [BibTex]


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Magnetically actuated propulsion at low Reynolds numbers: towards nanoscale control

Fischer, P., Ghosh, A.

NANOSCALE, 3(2):557-563, 2011 (article)

Abstract
Significant progress has been made in the fabrication of micron and sub-micron structures whose motion can be controlled in liquids under ambient conditions. The aim of many of these engineering endeavors is to be able to build and propel an artificial micro-structure that rivals the versatility of biological swimmers of similar size, e. g. motile bacterial cells. Applications for such artificial ``micro-bots'' are envisioned to range from microrheology to targeted drug delivery and microsurgery, and require full motion-control under ambient conditions. In this Mini-Review we discuss the construction, actuation, and operation of several devices that have recently been reported, especially systems that can be controlled by and propelled with homogenous magnetic fields. We describe the fabrication and associated experimental challenges and discuss potential applications.

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Video - Nanospropellers DOI [BibTex]


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Design and application of a wire-driven bidirectional telescopic mechanism for workspace expansion with a focus on shipbuilding tasks

Lee, D., Chang, D., Shin, Y., Son, D., Kim, T., Lee, K., Kim, J.

Advanced Robotics, 25, 2011 (article)

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[BibTex]

[BibTex]


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Weak value amplified optical activity measurements

Pfeifer, M., Fischer, P.

Opt. Express, 19(17):16508-16517, OSA, 2011 (article)

Abstract
We present a new form of optical activity measurement based on a modified weak value amplification scheme. It has recently been shown experimentally that the left- and right-circular polarization components refract with slightly different angles of refraction at a chiral interface causing a linearly polarized light beam to split into two. By introducing a polarization modulation that does not give rise to a change in the optical rotation it is possible to differentiate between the two circular polarization components even after post-selection with a linear polarizer. We show that such a modified weak value amplification measurement permits the sign of the splitting and thus the handedness of the optically active medium to be determined. Angular beam separations of Δθ ∼ 1 nanoradian, which corresponds to a circular birefringence of Δn ∼ 1 × 10−9, could be measured with a relative error of less than 1%.

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link (url) DOI [BibTex]

link (url) DOI [BibTex]


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Waalbot II: Adhesion recovery and improved performance of a climbing robot using fibrillar adhesives

Murphy, M. P., Kute, C., Mengüç, Y., Sitti, M.

The International Journal of Robotics Research, 30(1):118-133, SAGE Publications Sage UK: London, England, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Automated Control of AFM Based Nanomanipulation

Xie, H., Onal, C., Régnier, S., Sitti, M.

In Atomic Force Microscopy Based Nanorobotics, pages: 237-311, Springer Berlin Heidelberg, 2011 (incollection)

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[BibTex]

[BibTex]


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Automated 2-D nanoparticle manipulation using atomic force microscopy

Onal, C. D., Ozcan, O., Sitti, M.

IEEE Transactions on Nanotechnology, 10(3):472-481, IEEE, 2011 (article)

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[BibTex]

[BibTex]


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Design and analysis of a magnetically actuated and compliant capsule endoscopic robot

Yim, S., Sitti, M.

In Robotics and Automation (ICRA), 2011 IEEE International Conference on, pages: 4810-4815, 2011 (inproceedings)

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[BibTex]

[BibTex]


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Micro-scale propulsion using multiple flexible artificial flagella

Singleton, J., Diller, E., Andersen, T., Regnier, S., Sitti, M.

In Intelligent Robots and Systems (IROS), 2011 IEEE/RSJ International Conference on, pages: 1687-1692, 2011 (inproceedings)

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Project Page [BibTex]

Project Page [BibTex]


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Biaxial mechanical modeling of the small intestine

Bellini, C., Glass, P., Sitti, M., Di Martino, E. S.

Journal of the mechanical behavior of biomedical materials, 4(8):1727-1740, Elsevier, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Teleoperation Based AFM Manipulation Control

Xie, H., Onal, C., Régnier, S., Sitti, M.

In Atomic Force Microscopy Based Nanorobotics, pages: 145-235, Springer Berlin Heidelberg, 2011 (incollection)

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[BibTex]

[BibTex]


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Descriptions and challenges of AFM based nanorobotic systems

Xie, H., Onal, C., Régnier, S., Sitti, M.

In Atomic Force Microscopy Based Nanorobotics, pages: 13-29, Springer Berlin Heidelberg, 2011 (incollection)

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[BibTex]

[BibTex]


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Control of multiple heterogeneous magnetic micro-robots on non-specialized surfaces

Diller, E., Floyd, S., Pawashe, C., Sitti, M.

In Robotics and Automation (ICRA), 2011 IEEE International Conference on, pages: 115-120, 2011 (inproceedings)

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[BibTex]

[BibTex]


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Tip based robotic precision micro/nanomanipulation systems

Onal, C., Sumer, B., Ozcan, O., Nain, A., Sitti, M.

In SPIE Defense, Security, and Sensing, pages: 80580M-80580M, 2011 (inproceedings)

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[BibTex]

[BibTex]


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Design of a miniature integrated multi-modal jumping and gliding robot

Woodward, M. A., Sitti, M.

In Intelligent Robots and Systems (IROS), 2011 IEEE/RSJ International Conference on, pages: 556-561, 2011 (inproceedings)

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Project Page [BibTex]

Project Page [BibTex]


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Assembly and disassembly of magnetic mobile micro-robots towards deterministic 2-D reconfigurable micro-systems

Diller, E., Pawashe, C., Floyd, S., Sitti, M.

The International Journal of Robotics Research, 30(14):1667-1680, SAGE Publications Sage UK: London, England, 2011 (article)

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[BibTex]

[BibTex]


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Applications of AFM Based Nanorobotic Systems

Xie, H., Onal, C., Régnier, S., Sitti, M.

In Atomic Force Microscopy Based Nanorobotics, pages: 313-342, Springer Berlin Heidelberg, 2011 (incollection)

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[BibTex]

[BibTex]


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Free flight simulations and pitch and roll control experiments of a sub-gram flapping-flight micro aerial vehicle

Hines, L. L., Arabagi, V., Sitti, M.

In Robotics and Automation (ICRA), 2011 IEEE International Conference on, pages: 1-7, 2011 (inproceedings)

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Project Page [BibTex]

Project Page [BibTex]


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Modeling of stochastic motion of bacteria propelled spherical microbeads

Arabagi, V., Behkam, B., Cheung, E., Sitti, M.

Journal of Applied Physics, 109(11):114702, AIP, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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The effect of aspect ratio on adhesion and stiffness for soft elastic fibres

Aksak, B., Hui, C., Sitti, M.

Journal of The Royal Society Interface, 8(61):1166-1175, The Royal Society, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Chemotactic behavior and dynamics of bacteria propelled microbeads

Kim, Dongwook, Liu, Albert, Stitti, Metin

In Intelligent Robots and Systems (IROS), 2011 IEEE/RSJ International Conference on, pages: 1674-1679, 2011 (inproceedings)

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Project Page [BibTex]

Project Page [BibTex]


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Nanomechanics of AFM based nanomanipulation

Xie, H., Onal, C., Régnier, S., Sitti, M.

In Atomic Force Microscopy Based Nanorobotics, pages: 87-143, Springer Berlin Heidelberg, 2011 (incollection)

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[BibTex]

[BibTex]


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Under-actuated tank-like climbing robot with various transitioning capabilities

Seo, T., Sitti, M.

In Robotics and Automation (ICRA), 2011 IEEE International Conference on, pages: 777-782, 2011 (inproceedings)

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[BibTex]

[BibTex]


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Enhancing adhesion of biologically inspired polymer microfibers with a viscous oil coating

Cheung, E., Sitti, M.

The Journal of Adhesion, 87(6):547-557, Taylor & Francis Group, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Rotating magnetic micro-robots for versatile non-contact fluidic manipulation of micro-objects

Diller, E., Ye, Z., Sitti, M.

In Intelligent Robots and Systems (IROS), 2011 IEEE/RSJ International Conference on, pages: 1291-1296, 2011 (inproceedings)

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Project Page [BibTex]

Project Page [BibTex]


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Instrumentation Issues of an AFM Based Nanorobotic System

Xie, H., Onal, C., Régnier, S., Sitti, M.

In Atomic Force Microscopy Based Nanorobotics, pages: 31-86, Springer Berlin Heidelberg, 2011 (incollection)

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[BibTex]

[BibTex]


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Piezoelectric polymer fiber arrays for tactile sensing applications

Sümer, B., Aksak, B., Şsahin, K., Chuengsatiansup, K., Sitti, M.

Sensor Letters, 9(2):457-463, American Scientific Publishers, 2011 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Assembly and disassembly of magnetic mobile micro-robots towards deterministic 2-D reconfigurable micro-systems

Pawashe, C., Diller, E., Floyd, S., Sitti, M.

In Robotics and Automation (ICRA), 2011 IEEE International Conference on, pages: 261-266, 2011 (inproceedings)

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[BibTex]

[BibTex]


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Stochastic dynamics of bacteria propelled spherical micro-robots

Arabagi, V., Behkam, B., Sitti, M.

In Intelligent Robots and Systems (IROS), 2011 IEEE/RSJ International Conference on, pages: 3937-3942, 2011 (inproceedings)

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[BibTex]

[BibTex]


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Control methodologies for a heterogeneous group of untethered magnetic micro-robots

Floyd, S., Diller, E., Pawashe, C., Sitti, M.

The International Journal of Robotics Research, 30(13):1553-1565, SAGE Publications, 2011 (article)

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[BibTex]

[BibTex]

1998


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Surface second-order nonlinear optical activity

Fischer, P., Buckingham, A.

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 15(12):2951-2957, 1998 (article)

Abstract
Following the recent observation of a large second-harmonic intensity difference from a monolayer of chiral molecules with left and right circularly polarized light, the scattering theory is generalized and extended to predict linear and circular intensity differences for the more Versatile sum-frequency spectroscopy. Estimates indicate that intensity differences should be detectable for a typical experimental arrangement. The second-order nonlinear surface susceptibility tensor is given for different surface point groups in the electric dipole approximation; it is shown that nonlinear optical activity phenomena unambiguously probe molecular chirality only for molecular monolayers that are symmetric about the normal. Other surface symmetries can give rise to intensity differences from monolayers composed of achiral molecules. A water surface is predicted to show Linear and nonlinear optical activity in the presence of an electric field parallel to the surface. (C) 1998 Optical Society of America {[}S0740-3224(98)01311-3] OCIS codes: 190.0190, 190.4350, 240.6490.

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DOI [BibTex]

1998


DOI [BibTex]


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Linear electro-optic effect in optically active liquids

Buckingham, A., Fischer, P.

CHEMICAL PHYSICS LETTERS, 297(3-4):239-246, 1998 (article)

Abstract
A linear effect of an electrostatic field F on the intensity of sum- and difference-frequency generation in a chiral liquid is predicted. It arises in the electric dipole approximation. The effect changes sign with the enantiomer and on reversing the direction of the electrostatic field. The sum-frequency generator chi(alpha beta gamma)((2)) (-omega(3);omega(1),omega(2)), where omega(3) = omega(1) + omega(2), and the electric field-induced sum-frequency generator chi(alpha beta gamma delta)((3))(-omega(3);omega(1),omega(2),0)F-delta interfere and their contributions to the scattering power can be distinguished. Encouraging predictions are given for a typical experimental arrangement. (C) 1998 Elsevier Science B.V. All rights reserved.

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DOI [BibTex]

DOI [BibTex]


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Monolayers of hexadecyltrimethylammonium p-tosylate at the air-water interface. 1. Sum-frequency spectroscopy

Bell, G., Li, Z., Bain, C., Fischer, P., Duffy, D.

JOURNAL OF PHYSICAL CHEMISTRY B, 102(47):9461-9472, 1998 (article)

Abstract
Sum-frequency vibrational spectroscopy has been used to determine the structure of monolayers of the cationic surfactant, hexadecyltrimethylammonium p-tosylate (C(16)TA(+)Ts(-)), at the surface of water. Selective deuteration of the cation or the anion allowed the separate detection of sum-frequency spectra of the surfactant and of counterions that are bound to the monolayer. The p-tosylate ions an oriented with their methyl groups pointing away from the aqueous subphase and with the C-2 axis tilted, on average, by 30-40 degrees from the surface normal. The vibrational spectra of C(16)TA(+) indicate that the number of gauche defects in the monolayer does not change dramatically when bromide counterions are replaced by p-tosylate. The ends of the hydrocarbon chains of C16TA+ are, however, tilted much further from the surface normal in the presence of p-tosylate than in the presence of bromide. A quantitative analysis of the sum-frequency spectra requires a knowledge of the molecular hyperpolarizability tensor: the role of ab initio calculations and Raman spectroscopy in determining the components of this tensor is discussed.

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DOI [BibTex]

DOI [BibTex]


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Ultraviolet resonance Raman study of drug binding in dihydrofolate reductase, gyrase, and catechol O-methyltransferase

Couling, V., Fischer, P., Klenerman, D., Huber, W.

BIOPHYSICAL JOURNAL, 75(2):1097-1106, 1998 (article)

Abstract
This paper presents a study of the use of ultraviolet resonance Raman (UVRR) spectroscopic methods as a means of elucidating aspects of drug-protein interactions. Some of the RR vibrational bands of the aromatic amino acids tyrosine and tryptophan are sensitive to the microenvironment, and the use of UV excitation radiation allows selective enhancement of the spectral features of the aromatic amino acids, enabling observation specifically of their change in microenvironment upon drug binding. The three drug-protein systems investigated in this study are dihydrofolate reductase with its inhibitor trimethoprim, gyrase with novobiocin, and catechol O-methyltransferase with dinitrocatechol. It is demonstrated that UVRR spectroscopy has adequate sensitivity to be a useful means of detecting drug-protein interactions in those systems for which the electronic absorption of the aromatic amino acids changes because of hydrogen bonding and/or possible dipole-dipole and dipole-polarizability interactions with the ligand.

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DOI [BibTex]

DOI [BibTex]


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Tele-nanorobotics using an atomic force microscope as a nanorobot and sensor

Sitti, M., Hashimoto, H.

Advanced Robotics, 13(4):417-436, Taylor & Francis, 1998 (article)

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[BibTex]

[BibTex]


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Nano tele-manipulation using virtual reality interface

Sitti, M., Horiguchi, S., Hashimoto, H.

In Industrial Electronics, 1998. Proceedings. ISIE’98. IEEE International Symposium on, 1, pages: 171-176, 1998 (inproceedings)

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[BibTex]

[BibTex]


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Tele-nanorobotics using atomic force microscope

Sitti, M., Hashimoto, H.

In Intelligent Robots and Systems, 1998. Proceedings., 1998 IEEE/RSJ International Conference on, 3, pages: 1739-1746, 1998 (inproceedings)

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[BibTex]

[BibTex]


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2D micro particle assembly using atomic force microscope

Sitti, M., Hirahara, K., Hashimoto, H.

In Micromechatronics and Human Science, 1998. MHS’98. Proceedings of the 1998 International Symposium on, pages: 143-148, 1998 (inproceedings)

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[BibTex]

[BibTex]


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Macro to nano tele-manipulation through nanoelectromechanical systems

Sitti, M., Hashimoto, H.

In Industrial Electronics Society, 1998. IECON’98. Proceedings of the 24th Annual Conference of the IEEE, 1, pages: 98-103, 1998 (inproceedings)

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[BibTex]

[BibTex]