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2003


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New electro-optic effect: Sum-frequency generation from optically active liquids in the presence of a dc electric field

Fischer, P., Buckingham, A., Beckwitt, K., Wiersma, D., Wise, F.

PHYSICAL REVIEW LETTERS, 91(17), 2003 (article)

Abstract
We report the observation of sum-frequency signals that depend linearly on an applied electrostatic field and that change sign with the handedness of an optically active solute. This recently predicted chiral electro-optic effect exists in the electric-dipole approximation. The static electric field gives rise to an electric-field-induced sum-frequency signal (an achiral third-order process) that interferes with the chirality-specific sum-frequency at second order. The cross-terms linear in the electrostatic field constitute the effect and may be used to determine the absolute sign of second- and third-order nonlinear-optical susceptibilities in isotropic media.

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DOI [BibTex]

2003


DOI [BibTex]


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Chiral and achiral contributions to sum-frequency generation from optically active solutions of binaphthol

Fischer, P., Wise, F., Albrecht, A.

JOURNAL OF PHYSICAL CHEMISTRY A, 107(40):8232-8238, 2003 (article)

Abstract
The nonlinear sum- and difference-frequency generation spectroscopies can be probes of molecular chirality in optically active systems. We present a tensorial analysis of the chirality-specific electric-dipolar sum-frequency-generation susceptibility and the achiral electric-quadrupolar and magnetic-dipolar nonlinearities at second order in isotropic media. The chiral and achiral contributions to the sum-frequency signal from the bulk of optically active solutions of 1,1'-bi-2-naphthol (2,2'-dehydroxy-1,1'-binaphthyl) can be distinguished, and the former dominates. Ab initio computations reveal the dramatic resonance enhancement that the isotropic component of the electric-dipolar three-wave mixing hyperpolarizability experiences. Away from resonance its magnitude rapidly decreases, as-unlike the vector component-it is zero in the static limit. The dispersion of the first hyperpolarizability is computed by a configuration interaction singles sum-over-states approach with explicit regard to the Franck-Condon active vibrational substructure for all resonant electronic states.

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DOI [BibTex]

DOI [BibTex]


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Synthetic gecko foot-hair micro/nano-structures as dry adhesives

Sitti, M., Fearing, R. S.

Journal of adhesion science and technology, 17(8):1055-1073, Taylor & Francis Group, 2003 (article)

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Project Page [BibTex]

Project Page [BibTex]


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Teleoperated touch feedback from the surfaces at the nanoscale: modeling and experiments

Sitti, M., Hashimoto, H.

IEEE/ASME transactions on mechatronics, 8(2):287-298, IEEE, 2003 (article)

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[BibTex]

[BibTex]


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High aspect ratio polymer micro/nano-structure manufacturing using nanoembossing, nanomolding and directed self-assembly

Sitti, M.

In ASME 2003 International Mechanical Engineering Congress and Exposition, pages: 293-297, 2003 (inproceedings)

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[BibTex]

[BibTex]


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Nsf workshop on future directions in nano-scale systems, dynamics and control

Sitti, M.

In Automatic Control Conference (ACC), 2003 (inproceedings)

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[BibTex]

[BibTex]


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3-D nano-fiber manufacturing by controlled pulling of liquid polymers using nano-probes

Nain, A. S., Sitti, M.

In Nanotechnology, 2003. IEEE-NANO 2003. 2003 Third IEEE Conference on, 1, pages: 60-63, 2003 (inproceedings)

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[BibTex]

[BibTex]


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Scaled teleoperation system for nano-scale interaction and manipulation

Sitti, M., Aruk, B., Shintani, H., Hashimoto, H.

Advanced Robotics, 17(3):275-291, Taylor & Francis Group, 2003 (article)

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[BibTex]

[BibTex]


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Manufacturing of two and three-dimensional micro/nanostructures by integrating optical tweezers with chemical assembly

Castelino, K., Satyanarayana, S., Sitti, M.

In Nanotechnology, 2003. IEEE-NANO 2003. 2003 Third IEEE Conference on, 1, pages: 56-59, 2003 (inproceedings)

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[BibTex]

[BibTex]


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Atomic force microscope probe based controlled pushing for nano-tribological characterization

Sitti, M.

IEEE/ASME Transactions on Mechatronics, 8(3), 2003 (article)

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[BibTex]


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Efficient charge recovery method for driving piezoelectric actuators with quasi-square waves

Campolo, D., Sitti, M., Fearing, R. S.

IEEE transactions on ultrasonics, ferroelectrics, and frequency control, 50(3):237-244, IEEE, 2003 (article)

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[BibTex]

[BibTex]


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Synthetic gecko foot-hair micro/nano-structures for future wall-climbing robots

Sitti, M., Fearing, R. S.

In Robotics and Automation, 2003. Proceedings. ICRA’03. IEEE International Conference on, 1, pages: 1164-1170, 2003 (inproceedings)

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[BibTex]

[BibTex]


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Piezoelectrically actuated four-bar mechanism with two flexible links for micromechanical flying insect thorax

Sitti, M.

IEEE/ASME transactions on mechatronics, 8(1):26-36, IEEE, 2003 (article)

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[BibTex]


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Biomimetic propulsion for a swimming surgical micro-robot

Edd, J., Payen, S., Rubinsky, B., Stoller, M. L., Sitti, M.

In Intelligent Robots and Systems, 2003.(IROS 2003). Proceedings. 2003 IEEE/RSJ International Conference on, 3, pages: 2583-2588, 2003 (inproceedings)

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Project Page [BibTex]

Project Page [BibTex]

2001


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Isotropic second-order nonlinear optical susceptibilities

Fischer, P., Buckingham, A., Albrecht, A.

PHYSICAL REVIEW A, 64(5), 2001 (article)

Abstract
The second-order nonlinear optical susceptibility, in the electric dipole approximation, is only nonvanishing for materials that are noncentrosymmetric. Should the medium be isotropic, then only a chiral system. such as an optically active liquid, satisfies this symmetry requirement. We derive the quantum-mechanical form of the isotropic component of the sum- and difference-frequency susceptibility and discuss its unusual spectral properties. We show that any coherent second-order nonlinear optical process in a system of randomly oriented molecules requires the medium to be chiral. and the incident frequencies to be different and nonzero. Furthermore, a minimum of two nondegenerate excited molecular states are needed for the isotropic part of the susceptibility to be nonvanishing. The rotationally invariant susceptibility is zero in the static field limit and shows exceptionally sensitive resonance and dephasing effects that are particular to chiral centers.

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DOI [BibTex]

2001


DOI [BibTex]


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Reply to “Comment on ‘Phenomenological damping in optical response tensors’”

Buckingham, A., Fischer, P.

PHYSICAL REVIEW A, 63(4), 2001 (article)

Abstract
We show that damping factors must not be incorporated in the perturbation of the ground state by a static electric field. If they are included, as in the theory of Stedman et al. {[}preceding Comment. Phys. Rev. A 63, 047801 (2001)], then there would be an electric dipole in the y direction induced in a hydrogen atom in the M-s = + 1/2 state by a static electric field in the x direction. Such a dipole is excluded by symmetry.

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DOI [BibTex]


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Survey of nanomanipulation systems

Sitti, M.

In Nanotechnology, 2001. IEEE-NANO 2001. Proceedings of the 2001 1st IEEE Conference on, pages: 75-80, 2001 (inproceedings)

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[BibTex]

[BibTex]


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Nanotribological characterization system by AFM based controlled pushing

Sitti, M.

In Nanotechnology, 2001. IEEE-NANO 2001. Proceedings of the 2001 1st IEEE Conference on, pages: 99-104, 2001 (inproceedings)

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[BibTex]

[BibTex]


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Towards flapping wing control for a micromechanical flying insect

Yan, J., Wood, R. J., Avadhanula, S., Sitti, M., Fearing, R. S.

In Robotics and Automation, 2001. Proceedings 2001 ICRA. IEEE International Conference on, 4, pages: 3901-3908, 2001 (inproceedings)

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[BibTex]

[BibTex]


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Man-machine interface for micro/nano manipulation with an afm probe

Aruk, B., Hashimoto, H., Sitti, M.

In Nanotechnology, 2001. IEEE-NANO 2001. Proceedings of the 2001 1st IEEE Conference on, pages: 151-156, 2001 (inproceedings)

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[BibTex]

[BibTex]


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Development of PZT and PZN-PT based unimorph actuators for micromechanical flapping mechanisms

Sitti, M., Campolo, D., Yan, J., Fearing, R. S.

In Robotics and Automation, 2001. Proceedings 2001 ICRA. IEEE International Conference on, 4, pages: 3839-3846, 2001 (inproceedings)

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[BibTex]

[BibTex]


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Thorax Design and Wing Control for a Micromechanical Flying Insect

Yan, J, Ayadhanula, S, Sitti, M, Wood, RJ, Fearing, RS

In PROCEEDINGS OF THE ANNUAL ALLERTON CONFERENCE ON COMMUNICATION CONTROL AND COMPUTING, 39(2):952-961, 2001 (inproceedings)

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[BibTex]

[BibTex]


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PZT actuated four-bar mechanism with two flexible links for micromechanical flying insect thorax

Sitti, M.

In Robotics and Automation, 2001. Proceedings 2001 ICRA. IEEE International Conference on, 4, pages: 3893-3900, 2001 (inproceedings)

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[BibTex]

[BibTex]


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Wing transmission for a micromechanical flying insect

Yan, J., Avadhanula, S., Birch, J., Dickinson, M., Sitti, M., Su, T., Fearing, R.

Journal of Micromechatronics, 1(3):221-237, Brill, 2001 (article)

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[BibTex]

[BibTex]


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Development of a scaled teleoperation system for nano scale interaction and manipulation

Sitti, M., Aruk, B., Shintani, H., Hashimoto, H.

In Robotics and Automation, 2001. Proceedings 2001 ICRA. IEEE International Conference on, 1, pages: 860-867, 2001 (inproceedings)

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[BibTex]

[BibTex]